I'm not certain but I'd bet a dollar that it's all about money and contracts. Interestingly, Amazon doesn't seem to offer a streaming option at all. They will sell you all seasons on DVD though.
In 1995 when the actors/producers signed contracts and entered into their various deals that determined their share of the rerun and DVD payments, no one had any idea that streaming or digital were on the horizon. To offer digital copies somebody has to go back to all parties and renegotiate. Chances are somebody who appeared in season 1, for whatever reason, either wouldn't or couldn't agree to a new deal. The DVD rights were negotiated back in the 90s so DVDs are available but season 1 on digital isn't.