The 5th drive installation should work, and boot camp isn't needed, as it's an entirely separate drive.
Download the
AHCI drivers, and do a fresh installation of windows. When you get to the screen of drives and partitions, go to Load Driver, and feed it the AHCI drivers. Once it's done, then hit REFRESH*. Pick the drive, and go.
The only possible issue I can think of (along the lines of your conversation with Apple), is they blew it with the firmware. That is, the RAID card takes over all the SATA ports, rather than just 4.
VMWare would have a cost in resources, and overall performance would depend on what you have in the system (memory), and how loaded you run it.
Do the trial if you have to, but try the AHCI drivers first. Free can't be beat.
*Don't forget this step, otherwise you'd get an error message at the bottom of the install screen, and it won't install to the drive.
Hope this helps, and good luck.