I spend my life transferring files - data, pdf, word, excel, zip and database backup files.
Some of the files are critical, others not so. If I really care, I run
crc32 on the command line:
Most of the time that's just to verify a backup got moved correctly so it'll restore later.
Who is going to be modifying your PDF files anyway,
@BeautifulWoman_1984 ? If you're not a large corporation or a Nation state, the answer is invariably going to be "no-one"
If you're this concerned, compress the file with a password and send that to the destination. If it decompresses OK then you're fine.
Except...what if some has a keylogger and knows your password and...
Again, trust me, you're like the rest of us: an insignificant nobody. I don't mean that as an insult, more of a affirmation that you're blowing all of this out of proportion.
I've worked for banks and been a military contractor in my day - even they don't get this paranoid - and they can get quite wacky (like, from the mid 1990s I read a the Classified document that specified what color floppy disks should be for each level, red for top secret etc., but no-one without security Clearence would know that they should only use black floppy disks - and you were not allowed to tell unclassified folk that either, etc...)
Breath and just copy away. You really honestly will be fine.