Heh, I use a confusing, but often used term here, sorry.
so called "ATA-66" is actually ATA-5 which has 66MB/s throughput (theoretically, but in real life with IDE drives you usually get arround 35MB)
"ATA-33" is ATA-4 = 33MB/s (theoretically, without minus the so called overhead vor protocolls)
Then there is ATA-3, which is ATA-2 plus SMART-Functions etc.
ATA-2/ATA-3 is 16MB/s.
Well, usually certain UDMA versions come on top, that make different speeds for otherwise reported Buses (like ATA-4 33MB can get 100MB), but that isn't the case for PowerMacs. They have the lowest UDMA revision. I say all this as if I knew, what I am talking about, but actually I just repeat it the vague way I understand it.
PowerMacs G4 ATA-speeds:
PowerMacs with dark-blueish /graphite case:
HDD = ...
ODD =
Silver PowerMacs:
HDD =
ODD =
Silver with mirror front:
HDD =
HDD =
ODD =
Oh, I have to go to bed, but you can look up the ATA-speeds under everymac.com -> all PowerMacs.
You will find it interesting, that the BUS for the optical drives (CD/DVD) is ATA-3 with 16MB/s in many G4s, I think the MDD has an ATA-66 optical Drive BUS.
That is more interesting, when you know, that the Apple laptops had faster optical drive BUSes, than their same time contemporary PowerMacs. Which is why connecting a HDD to the DVD-drive-cable is so slow in PowerMac G4s and will only make sense for certain uses.