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It would have been 10.2, the first OS X I ever used. Newer versions were incremental improvements from there, but 10.2 was leaps and bounds ahead of Windows XP.
I had a similar experience. I got a secondhand G4 Mac Pro to see what all the fuss about Macs that I was hearing was about. I didn’t even look at OS 9, and put OS X on it. 10.2 was what I got hold of, and it converted me away from XP.
 
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