It's technically possible to use mismatched CPU's, but you can run into issues (it's not a guarantee you will though). But a matched set solves potential issues, assuming it's possible to get them at the same time (namely the same steppings; exact P/N's will give you this, but it's not W55xx for example, but Intel's numbers off the ark site - 4 letter scheme that accompanies the W/E/Xyyyy, such as SLAN for example). It will give the details as to a tray or retail package, and the stepping information. Not hard, as if you order the same exact part from a vendor, it will almost always be the same (same palate/tray, from the same production batch).
Up to you, but if you can save the funds to purchase both at the same time, you'll be in a better situation.