I had a episode of The Office on my iMac. After I synced my ipad I couldn't find it anywhere. Does the ipad even hold TV shows?
If it's not in the video app, hook the iPad up to your 'puter, and drag and drop the tv show into your iPad (from inside of iTunes of course). The heck with all that syncing crap. (okay, maybe one day I'll learn how to poperly set up syncing, but today is not the day).
If you are going to drag and drop, you need to set your iPad to manually manage music first. A lot of people who do this checked the "manually manage" check box once, a long time ago, and forget that they had to do it.