Or, try using ONLY the Samsung memory. Boot up to a NVRAM reset, by holding Option-Command-P and R.
You absolutely should get a boot chime during a boot while holding those 4 keys. If you get a boot chime, continue to hold the same 4 keys, until you hear the boot chime 2 more times, then release the keys and let your Mac boot normally. Does it boot successfully this time? If yes, do a normal shut down, and add the other ram. Boot with the same NVRAM reset, again holding the keys until you get the boot chime 2 more times. Should be good now. -- or, not. If your iMac still won't boot with that Samsung RAM, then return, and try a different brand.