Edit: incase anyone's wondering, it's currently used solely for FileVault 2's full disk encryption. That's about the extent of its capabilities for now. It's a full logical disk management system though, it's just in the early stages.
Core Storage, being a logical volume manager, doesn't solve the data integrity problems HFS+ has. The main appeal of ZFS to many is that it addresses silent data corruption.
I really don't want to run a linux or BSD box. The whole goal of using a Mac was to make getting software easy. I wanted to have iTunes running in the background to share music and movies in the home, along with a variety of DLNA software (my Samsung and Vizio TVs are incredibly picky about the host DLNA software).
The latest FreeNAS 8.2 release has support for plugins. Looks like DLNA and an iTunes server are already available. Everything (including volume management, sharing, etc) is configured through a web GUI. Honestly, it was easier for me to set up than OS X file sharing. Using an old mATX case/PSU and some leftover RAM/drives, I was able to get a Sandy Bridge-based FreeNAS box going for ~$100.