I wasn't able to use this on my iPhone 6 until I dealt with about 6 people from AT&T side. (I purchased unlocked "tmobile" phone and put old AT&T sim inside.
Apparently the 9th and 10th digit of SIM card must be >= 27 to support VoLTE. Mine was not, they sent me a new SIM in mail and I was able to get it setup ~48hours of discovering that issue (since I didn't want to go deal with the sales people at the store)
You're not missing much. Their deployment of it is MUCH different than TMO. I have a TMO iPhone 6s and an ATT iPhone 6s, and TMO's is 100000x better. Theirs is wifi-first in priority, so anytime you have internet, it just works, and it doesn't care about your location... on a plane over Sri Lanka, it works. In a train in the fields of eastern France, it works. In a hotel room in Sydney, yep. Same experience for voice\text\imessage as home.
ATT... LOL, not so much. Once you leave the US, the geo-location figures it out... no more Wifi calling for you. Now of course there are ways to trick it, but the idea is they don't want that... And there are ways to force it to wifi, but they don't want it. Yet another example of how ATT is trying to send the industry back to 1999, like their typical employee's mindset seems to be stuck.