Not in the least, right now. There has to be application-level support as well as OS-level support in order to fully take advantage of SLI. Not quite as sure about Crossfire.
Either way, the Pro apps will need to support SLI. Not just the operating system.
And remember: as soon as you enable SLI, you lose all but 1 monitor. There is no multi-monitor support for SLI from nVidia.
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Application level support? Where are you getting that from? SLI is driver enabled and driven. The 'application' just sees a faster graphics card, it doesn't need to know anything about what the graphics card is because it only talks to the driver and the driver can lie all it wants.
Well it seems SLI is single monitor only which does kind of suck.
As for 1 monitor, i can't verify this but i'm sure it isn't true. You lose the ability to run a monitor from the second card but both outputs on the main card should still work.