For the first one, assuming each point is equally likely for the dart to land, then the probability of landing in the shaded area = area of shaded part / total area
total area = 16*pi
area of shaded part = 16*pi - 12sqrt(3)
so probability = 1 - (3*sqrt(3) / 4*pi) = 0.5865
Where did these come from. Well, total area is easy, it's a circle so area is pi*r^2 = pi*4^2 = 16*pi
area of shaded part = area of circle - area of triangle.
Okay, how to find the area of the triangle. Divide up the big triangle into 3 identical isosceles triangles by drawing lines from the center to each vertex. Each of those isosceles triangles has two sides of length 4 and an angle of 120 degrees. Basic trig shows the area of each is 4*sqrt(3), so the big triangle has area 12*sqrt(3).