I did some "research" on this topic.
Because my experiences with old world Macs are based on the Powermac beige G3 mainly I confirm that this Mac works flawlessly with many PCI extension cards in OS 9.2.2, be it USB, FireWire 400, UltraATA133, SATA1 or DVI graphics.
The main reason for that is the PCI 2.1 revision that was introduced with the so called "Gossamer" G3 mainboard by Apple.
However, with these old world Macs USB and FireWire PCI cards should only feature a maximum of three (external) ports, better two.
OS9 USB extensions sometimes cannot detect multi-controller (multi-bus, multi-bridge) cards correctly such like a 5-ports USB card (despite having the good NEC 720100 chipset).
In addition the power requirements of such multi-port PCI cards (500mA per port) may exceed the internal power supply of the PCI slot.
For this reason installing an externally powered OS9 compliant USB hub is always highly recommended. This one for instance works great:
http://www.ebay.de/itm/USB-HUB-4-fa...3?pt=DE_Computer_Sonstige&hash=item5193a53edf
I don't know if the PM9600 already features PCI 2.1 standard. But for older than beige G3 Powermacs it seems generally advisable to use a 2+2 USB/FireWire combo card (coming with the recommended chipsets) or two separate PCI Cards featuring 2 or 3 ports each.
I'd look for a Mac specific vintage dual port USB 1.1, OHCI-compliant, OPTi-chip based PCI card such like:
MacAlly UH-275
Keyspan UPCI-2
Belkin F5U005
D-Link DSB-500
Some proposals for Texas Instruments TSB43 -chip based FireWire 400 IEEE-1394a cards with 6-pin buspower:
HP 515182-001
Adaptec AFW-4300B (red colored circuit board)
Belkin F5U503 rev.s