A couple of things.
1) once you know what pins to jump you can make it more permanent and safer (than the stupid paper-clip way) just by using a little ingenuity. Like, instead of going into the front of the connector you can enter thru the rear. You can use a piece of shielded solid core electrical wire like they use to wire a house. You can also remove the pins in question, strip the ends, and solder and/or twist them together and then shield them with electrical tape. The adaptors you linked to below look like they would work too, yes. The system function of those two pins is typically a push-on/off switch that shorts those two pins and thus starts the power up. It's a little more complicated but that's basically it.
2) Do not try to supply the 75W thru the 6-pin connector (to the GPU card) by using a SATA power connector which is rated at about one third of what you need. I can't remember if the SATA power is rated at 20W or 40W but it's NOT 75W so don't do it. It may even work for a year or something but you will be running your system very inappropriately and overdrawing thru/from some components not made or rated to support that. Those SATA Power to Molex Power adaptors are made for drives that don't happen to have a SATA power connector. I dunno of any drives that draw more than about 20W - peak - and typically it's about half that. You could probably run a fan or something but no way would I connect it up to the GPU in any way for the supply of power.
Yeah, as others have mentioned it doesn't actually connect to the Mac. There will be a bunch or connectors that will be left hanging like that. All you will need to use is the 6/8 pin connectors. The 6-pin is designed to supply 75W and the 8-pin is designed for 150W.
The GTX 690 (typically) is a 300W card. So you probably have two connectors; one 6-pin and one 8-pin. The Card Slot supplies 75W too so it probably looks like:
One 6-pin: 75W
One 8-pin: 150W
Card Edge: 75W
--------------------
Total pwr: 300W
And if it were me I would supply both the 6-pin and the 8-pin to such a card from your auxiliary PSU. If the card is two 8-pin connectors you have to supply both from the aux PSU.
You probably already know most of that but I thought I might reiterate a little.