Read carefully below.
Where you're lacking to understand, is you believe PVD is one specific process to apply a coating. That's not true. PVD can be used in many different forms and is not just a process. PVD is dynamic and doesn't specifically apply just as a process, it can be used separately as a coating, where DLC is only applied in one manner, look at it like it's a paint.
The most common applications that PVD does not apply a coating, is firearms. That's a heat treated process that uses
electroplating to provide a protective bond to the metal or a thin film that essentially is a protective layer, but does not have the hardness of DLC. Reason being because it's a substrate process that can be used on a variety of different types of metals and finishes, where DLC cannot be applied, because it won't adhere appropriately to the metal. Where a physical source is used for the metal content of the coating that combines with a gas to form the PVD coating, which is not transferable to all products.
PVD coating is particularly recommended for all those innovative quality products which require high chemical and technical features (resistance to abrasion, scratches, and corrosion) and at the same time offers a wide choice of chromatic colors.
PVD coatings, with a layer thickness in between 0,2m and 2 m, presents exceptional aesthetical features as well as it guarantees a very long life for the durability over DLC, bought you some of the same techniques, but PVD is more dynamic and how it can be applied to a specific product versus DLC.