in my limited computer knowledge when the AC power is applied to the psu/mobo combination you should have a standby led on , to indicate the presence of the 5vdc supply for the KB /mouse to bring the unit out of sleep
as you have proved the psu seems to switch on ( have you tested it with a load resistor ? )
is the PSU the correct one for the mobo , not sure is apple do but Hell do, they change the pin outs on the power header ( blew a mb because of this they had reconfigured the + and - 12 leads )
also the cpu/s and ram must be present to allow the MB to come up to power state
sorry i cannot be of more help but without some known/proven tested parts you will be chasing your tail , always assuming that that you do not have the diagnostic PCI riser card to test out the MB ( but then you would not be scratching your head over this )
as you have proved the psu seems to switch on ( have you tested it with a load resistor ? )
is the PSU the correct one for the mobo , not sure is apple do but Hell do, they change the pin outs on the power header ( blew a mb because of this they had reconfigured the + and - 12 leads )
also the cpu/s and ram must be present to allow the MB to come up to power state
sorry i cannot be of more help but without some known/proven tested parts you will be chasing your tail , always assuming that that you do not have the diagnostic PCI riser card to test out the MB ( but then you would not be scratching your head over this )