An interesting thing with NVMe boot, I have in my machine NVMe boot and also AHCI both via PCIe cards. when I just zapped the PRAM and NVRAM it switched from booting the NVMe drive to booting the AHCI drive. I think it maybe that the AHCI drive will be seen as priority after NVRAM zap.
On a separate note I just installed a LT-120 PCIe card with NVMe Samsung 951 drive to my single CPU Mac Pro and can report that it works very well, I have also added heat sinks to the NVMe drive. I will do a speed test shortly. thanks again to TisAlex for the boot rom
😎 below is the test, slower write speeds than the 951 AHCI drive by 200, but faster read speed by a little bit about 50 still a lot faster than SSD or SATA 2 or 3