In regards to hair and green: The biggest problem is with blond hair. I live in the middle of the Pacific, where people are dark, but you can do a lot while shooting already. Important is to light your green screen and talent separately, try to prevent green spill (hair light, back light and flagging help a lot). Modern day's software also helps you pull a great key. The spill suppressor in FCP6 was great already, but FCP X does a terrific job with keying.
There's an interesting discussion on Macbreak Studio, and another one on Pixelcorps' YouTube Channel
i have to say again that i have a very decent light and back drop set up. i still see spills, even noise in the DSLR shoot out link i posted, seems like the canon af100 might be the way to go since you get a decent video camera, nice sensor and choice of lens's, but i have to admit i am not a pro photographer or film maker, like i never went to school, i just have some friends over the last 15 years who are and sat in their shoots, i am more of a audio/video editor who wants to get more into shooting so my footage has more less what i am after., i did own several cameras during the hi 8 times and worked in TV news rooms as an editor between the Beta SP to hi 8 momentum., after that i went to AVID, AE, Premiere