You can't enable the RAID without losing your data. You have to wipe the drives. RAID0 anyway (you can build a mirrored, or RAID1 array with one drive with data on it and one blank drive, but not a striped RAID)
Worth it? I did it, but more for the capacity than the speed. Newegg had the 256GB Crucial M4's on sale so it was about a hundred bucks cheaper to get two 256GB M4's than one 512GB M4. Didn't want to mess with two drives, so by using RAID0 I get one 512GB volume. Read/Write speeds are insanely fast, but in the real world that doesn't matter as much as access times, which don't have significant improvements in a RAID0.
It really depends on what you do. If you constantly work with large files stored within the SSD's, then yeah, it'll scream. If you don't, it'll still scream, but you aren't likely to NOTICE the difference between one drive or two.
I'm not at all opposed to it though! I love it for that once in a while time when I need to work with or move a large file around and BAM it's just done... it's insanely fast.. that's all there is to it. In fact, my read speeds are so fast, they actually EXCEED SATA 6Gb/s speeds. That means that my RAID0 configuration is faster than any one, single SATA 6G drive can possibly be!
There is, of course, it's big drawback. One drive fails, it's all gone. SSD's are very reliable, but it's a myth to say that they are bulletproof. They still fail. In addition to doubling the speed, you are doubling the rate of failure. The solution, IMO, is just good regular backups. I use a Time Capsule, alternatively.. what are you doing with your old factory spinning hard drive? You could always stick that in a cheap $20 USB 3.0 enclosure and use it as a Time Machine backup source. I don't know what year your MBP is, but if you did two 256GB SSD's and had a 500GB Hard Drive (what came stock on my 2012 MBP), then you won't run into a scenario where you don't have enough room for a backup! I'd do a backup every few days with that (or every day, before I got my Time Capsule, I would plug my MBP into the charger at my desk in the evenings, plug in the USB3 drive, and start Time Machine and go to bed! Doesn't take very long, but a 'routine' like that meant it got a daily backup. Though now with a time capsule, it gets hourly backups!)
So anyway, bottom line, it's up you. It'll scream, but I wouldn't suggest doing it unless you have a 'backup plan' (no pun intended, hehe).
Also, bear in mind the drives need to be the same size. If they aren't, you'll lose some capacity. I'm not sure if Mac OS will build the RAID or not anyway, but some software RAID systems will. If they do, say you take a 512GB SSD and a 256GB SSD, you'll end up with a 512GB RAID. The reason is, it'll take your 256GB SSD, and then only 256GB worth of the other drive. You may be able to partition it though, and have a 512GB RAID in that situation, along with a separate 256GB partition, but at a hit in performance. It's just easier to have two drives of the same size!