The difference between gyroscope and accelerometer is that the former can sense rotation, the latter cannot. A 3 axis accelerometer has the ability to gauge the orientation of a stationary platform relative to the earths surface. If the platform happens to be in free fall, the acceleration will be shown to be zero. If it is only accelerating in a particular direction the acceleration will be indistinguishable from the acceleration being provided by the earths gravitational pull. So an accelerometer alone cannot be used to have an aircraft maintain a particular orientation.
A gyroscope on the other hand has the capability of measuring the rate of rotation around a particular axis. For instance if a gyroscope is used to gauge the rate of rotation around the roll axis of an aircraft, it will come up with a non zero roll value, so long as the aircraft continues to roll, but shows zero if the roll stops.