Out of curiosity: Did this work running older macOS versions with your current setup (Which versions?)?
The DCC
pages is not really conclusive (to me) which connector setup (only dual miniDP, not single miniDP?) supports it fully. At the very end of this page there is a list of several macOS tools to enabled brightness control with displays (and connections) capable to achieve it.
Unfortunately I own only a single (miniDP) connected external display which never supported native brightness control with 2009-2011 iMacs running High Sierra natively or later (OCLP).