According to the D2D FAQ it looks like the app uses location services to determine if you're scanning barcodes from your billing address or not. So, unless you live at the Best Buy you're scanning codes at (or at least have your mail sent there) then you probably will not be able to do it.
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That's an interesting one. I've also noticed, after rolling in non-iTMS titles to Movies Anywhere, that the original date of purchase holds across all of the services. So it it might be possible that Extras weren't available for that specific version of the movie?I don't have any of them downloaded. More to the point, my Hobbit movies aren't even badged iTunes Extras. Doesn't matter what I do though, they don't show as having extras available