It’s unfortunate unpairing the watch did not solve the issue for you. Here’s what I recommend:Here's another screenshot of a typical day. An hour of that SoT was between 9-10pm.
So my phone just chews through battery at a pretty constant rate without much going on.
View attachment 1864271
download and use this app to observe what apps are accessing logs and network during the day and night:

App Privacy Insights
App Privacy Insights provides an easy way to read through and analyze the new App Privacy Report NDJSON files from the new functionality of iOS / iPadOS, including network activities, permission usage logs and other event log. - No data leaves your device* - Import directly from settings -...
apps.apple.com
follow the instruction and give it a full 24 hours. You should be able to narrow down the apps this way. Good luck.