I charged mine to 100% last night, and left it plugged in at 100% for a couple hours before disconnecting and going to bed. That said, I have NOT calibrated the battery yet, nor have I let it get below 75% since I got it. When I woke up nearly 11 hours later, I was still at 99%.
I had bluetooth off, iCloud off, push on, wifi on, siri on, location based services on, notification center on (though I don't turn on apps for that, just mail/messages/calls/voicemails/weather).
Though, for whatever reason, it says I have 13 minutes of usage and 10 hours, 47 minutes of standby. The standby sounds fine, but I should have 0-1 minute of usage...didn't touch it at all after I unplugged it and went to bed until I pressed the home button to check the battery this morning.
One thing though--if you are going to test the battery, it would be a good idea to actually power the phone off completely and then back on at night right before you are about to test it to kill any background apps. I did this since there doesn't seem to be any real way to tell what apps are or aren't running in the background (double tapping the home button just shows you recent apps that have been used, not the ones running), so this way I knew I had no extraneous background processes running overnight.
Can't you just kill the background apps by closing everything in multi-tasking?
Nevermind. Looks like they are completely different.