Well, it's arrived, it's plugged in and WOW. Lots of people said I couldn't do this with the Thunderbolt station. Three screens - Laptop, one TB->Dvi, one HDMI->Dvi. So happy.
I've also got a Seagate 3Tb USB device attached, and a Lacie 2 Tb Little Disk on the thunderbolt chain.
I almost didn't order this as people said it wouldn't work. I almost didn't try it, but it was worth 15 mins of my time to try it out.....
I also didn't install any drivers. All I did was re-configure my audio out, and create a new location to use hard wired Ethernet rather than use wireless.
BTW, Macbook Pro early 2011 running Mavericks. Might even fire up Parallels now and see what happens with that!