No! I'm disappointed. I wonder if the 5s actually has VoLTE capabilities or if this is Apple limiting us again?
It's hard to say. I do know that AT&T requires your phone to be able to use their HD Voice feature for this to work. It only lists iPhone 6 and above as being able to have that feature. Maybe the quality was too poor without the HD Voice feature (just guessing). If thats the case it would be AT&T's doing. I do find it interesting on my iPhone 5s the Wi-Fi calling switch was there after iOS9 update. Now it's gone since I updated to iOS 9.0.2