I have not noticed major delays in booting time, except fot the very FIRST boot after exchanging the factory blade with the NVMe Samsung 960. A little extra time is indeed noticeable on every boot once the Apple logo appears with the gauge below. I don't know if the experts also refer to that phase as "boot time", but I have always thought of that as the OS loading phase.
I'm using the ST-NGFF2013-C adapter, which I got from the following link:
https://www.amazon.com/gp/product/B01CWWAENG/ref=oh_aui_detailpage_o00_s00?ie=UTF8&psc=1
I got two of those and installed one in my Mid 2013 13 inch MacBook Air, and the other in my cylinder Mac Pro (Late 2013) with a 3,5 GHz 6-Core Intel Xeon E5 and 16 GB of RAM.
Originally I got the previous gen. Sintech (much shorter) adapter for the MacBook Air and, the one I linked to above, for the Mac Pro, but decided to get a second one for the MacBook Air as well, as explained below.
With the shorter Sintech adapter, the MacBook Air would not resume from sleep after reopening the display. So I got another unit of the ST-NGFF2013-C.
I remember doing a reset of both the SMC and the PRAM on the MacBook Air, but have not done either on the cylinder Mac Pro. EDIT: Since I initially posted this, I decided to try SMC and PRAM reset on the Mac Pro too. It did not make any difference in booting/OS loading times.
Lastly, I did not time previous nor current boot times on either machine, so this is all based on how the machines seem to behave once turned on. Over regular usage, on the other hand, both machines are way more snappy in everything I do and I think the SSD upgrade is very much worthwhile.
YMMV.